3,794 research outputs found

    Statistical-grey consistent grey differential equation modelling

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    Includes abstract. Includes bibliographical references (p. 152-156)

    Contributions to statistical machine learning algorithm

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    This thesis's research focus is on computational statistics along with DEAR (abbreviation of differential equation associated regression) model direction, and that in mind, the journal papers are written as contributions to statistical machine learning algorithm literature

    On the zeros of solutions of any order of derivative of second order linear differential equations taking small functions

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    In this paper, we investigate the hyper-exponent of convergence of zeros of f(j)(z)−φ(z)(j∈N)f^{(j)}(z)-\varphi(z) (j\in N), where ff is a solution of second or k(≥2)k(\geq2) order linear differential equation, φ(z)≢0\varphi(z)\not\equiv0 is an entire function satisfying σ(φ)<σ(f)\sigma(\varphi)<\sigma(f) or σ2(φ)<σ2(f)\sigma_{2}(\varphi)<\sigma_{2}(f). We obtain some precise results which improve the previous results in [3, 5] and revise the previous results in [11, 13]. More importantly, these results also provide us a method to investigate the hyper-exponent of convergence of zeros of f(j)(z)−φ(z)(j∈N)f^{(j)}(z)-\varphi(z)(j\in N)

    The quantum solvation, adiabatic versus nonadiabatic, and Markovian versus non-Markovian nature of electron transfer rate processes

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    In this work, we revisit the electron transfer rate theory, with particular interests in the distinct quantum solvation effect, and the characterizations of adiabatic/nonadiabatic and Markovian/non-Markovian rate processes. We first present a full account for the quantum solvation effect on the electron transfer in Debye solvents, addressed previously in J. Theore. & Comput. Chem. {\bf 5}, 685 (2006). Distinct reaction mechanisms, including the quantum solvation-induced transitions from barrier-crossing to tunneling, and from barrierless to quantum barrier-crossing rate processes, are shown in the fast modulation or low viscosity regime. This regime is also found in favor of nonadiabatic rate processes. We further propose to use Kubo's motional narrowing line shape function to describe the Markovian character of the reaction. It is found that a non-Markovian rate process is most likely to occur in a symmetric system in the fast modulation regime, where the electron transfer is dominant by tunneling due to the Fermi resonance.Comment: 13 pages, 10 figures, submitted to J. Phys. Chem.
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